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Transition Metal and Rare Earth Compounds: Excited States, Transitions, Interactions II

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-15% su kodu: ENG15
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Akcija baigiasi: 2025-03-03
-15% su kodu: ENG15
503,95 
Įprasta kaina: 592,88 
-15% su kodu: ENG15
Kupono kodas: ENG15
Akcija baigiasi: 2025-03-03
-15% su kodu: ENG15
2025-02-28 592.8800 InStock
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Knygos aprašymas

There exists a large literature on the spectroscopic properties of copper(II) com- 9 pounds. This is due to the simplicity of the d electron configuration, the wide variety of stereochemistries that copper(II) compounds can adopt, and the f- xional geometric behavior that they sometimes exhibit [1]. The electronic and geometric properties of a molecule are inexorably linked and this is especially true with six-coordinate copper(II) compounds which are subject to a Jahn-T- ler effect.However,the spectral-structural correlations that are sometimes d- wn must often be viewed with caution as the information contained in a typical solution UV-Vis absorption spectrum of a copper(II) compound is limited. Meaningful spectral-structural correlations can be obtained in a related series of compounds where detailed spectroscopic data is available. In the fol- 4¿ lowing sections two such series are examined; the six-coordinate CuF and 6 2+ Cu(H O) ions doped as impurities in single crystal hosts.Using low tempera- 2 6 ture polarized optical spectroscopy and electron paramagnetic resonance, a very detailed picture can be drawn about the geometry of these ions in both their ground and excited electronic states. We then compare the spectrosco- cally determined structural data with that obtained from X-ray diffraction or EXAFS measurements.

Informacija

Serija: Topics in Current Chemistry
Leidėjas: Springer Berlin Heidelberg
Išleidimo metai: 2010
Knygos puslapių skaičius: 204
ISBN-10: 3642087574
ISBN-13: 9783642087578
Formatas: 235 x 155 x 12 mm. Knyga minkštu viršeliu
Kalba: Anglų

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