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In this thesis, N-substituted diethanolamine ligands have been employed in the syntheses of heterometallic FeIII-LnIII clusters. The reactions of a preformed [FeIII3O]7+ benzoate triangle, LnIII salts and the ligands in different solvents under normal or solvothermal conditions lead to several mixed FeIII-LnIII species with different topologies. Furthermore, new species stabilized under solvothermal conditions can be obtained via a solvothermal treatment of the FeIII-LnIII compounds which result from reactions conducted under normal conditions. The resulting compounds were structurally analyzed by single-crystal X-ray crystallography and X-ray powder diffraction. The magnetic properties and spectroscopic studies were investigated using magnetic susceptibility measurements and Mössbauer spectroscopy. Magnetic studies reveal that three analogous hexanuclear {FeIII4DyIII2} compounds as well as a {FeIII7DyIII4} compound display single molecule magnet behavior.
| Autorius: | Sihuai Chen |
| Leidėjas: | Cuvillier |
| Išleidimo metai: | 2014 |
| Knygos puslapių skaičius: | 162 |
| ISBN-10: | 3954048809 |
| ISBN-13: | 9783954048809 |
| Formatas: | 210 x 148 x 9 mm. Knyga minkštu viršeliu |
| Kalba: | Anglų |
Parašykite atsiliepimą apie „Syntheses, Structures and Properties of FeIII-LnIII Complexes using N-substituted Diethanolamine Ligands“
