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This book introduces readers to the use of formic acid for efficient organic synthesis. It describes the N-methylation of aromatic and aliphatic amines with formic acid using a boron-based catalyst [B(C6F5)3] in combination with silanes and without the need for an expensive transition metal catalyst. It also shows that formic acid interacts with alkynes and allyl alcohols through a carbonylation process that generates carbon monoxide in situ from nickel and palladium catalysis, respectively, doing away with the need to use high-pressure CO gas and offering a user-friendly and practical method for preparing functionalized ¿, ¿- and ¿, ¿-unsaturated carboxylic acids. The findings presented not only enrich the field of ¿C1 chemistry,¿ but also support the advancement of green and sustainable chemistry.
Autorius: | Ming-Chen Fu |
Serija: | Springer Theses |
Leidėjas: | Springer Nature Singapore |
Išleidimo metai: | 2021 |
Knygos puslapių skaičius: | 120 |
ISBN-10: | 9811576254 |
ISBN-13: | 9789811576256 |
Formatas: | 235 x 155 x 7 mm. Knyga minkštu viršeliu |
Kalba: | Anglų |
Parašykite atsiliepimą apie „Studies on Green Synthetic Reactions Based on Formic Acid from Biomass“